Abstract

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The present study examines the physicochemical parameters and heavy metal contents of soil from Okpella Mining Area in Edo State. Top soil samples and control samples from about 200m from the mining area were analyzed for their heavy metals content using Atomic Absorption Spectrometer (AAS) techniques. The pH, electrical conductivity and organic matter were determined using standard procedures. The soil pH ranged from 6.8 to 7.9 which show slightly acidic to alkaline conditions. The concentrations of the metals in mg/kg were as follows: Cu (23.03 to 170.83), Pb (3.50 to 10.59), Cd (0.70 to 1.93), Cr (0.75 to 8.74), Ni (5.0 to 34.52), Zn (3.29 to 25.46), Mn (3.49 to 22.50), Fe (22.03 to105.67), Co (9.99 to 64.43) and As (0.35 to 1.20). Inter elemental correlation showed that most of the metals investigated were of common origin. The mean concentrations of the metals were in the general order: Cu>Fe> Co> Ni> Zn>Mn>Pb>Cr>Cd>As. The concentrations of the metals at mining area were generally higher than control. With the exception of Cd, the concentration of other metals analyzed were within safe limit based on WHO standard. Results from pollution index assessment also show that Cd has higher degree of contamination. There is therefore need to monitor agricultural activities going on in this area so as to guard the safety of man and organisms in the area

Keywords: Mining, heavy metals, Pollution, Okpella, Limestone and Soil.