Research Article

Mineralogical and Chemical Evaluation of Agbaja Fireclay for Industrial Applications

1 Department of Glass and Silicate Technology, Ahmadu Bello University, Zaria
2 Department of Industrial Design, Faculty of Industrial Design, Ahmadu Bello University, Zaria
* Corresponding author: yayakubu096@gmail.com
Published: Jun, 2023
Pages: 46-52

Abstract

To evaluate the potential of Agbaja clay for industrial applications, a comprehensive analysis of its physico-chemical and mineralogical properties was undertaken. The clay exhibited a predominantly kaolinitic composition, as determined by X-ray powder diffraction (XRD), with halloysite and illite as minor constituents. The chemical analysis revealed significant alumina (Al₂O₃) and silica (SiO₂) content at 38.68 wt% and 39.47 wt%, respectively, along with negligible alkali oxide impurities. The clay demonstrated plastic behavior with an Atterberg Plasticity Index of 15.45% and a neutral pH of 6.61. Based on these findings, Agbaja clay is deemed suitable for a wide range of applications including the production of refractory materials, vitreous ceramics, and as a filler in paper, rubber, plastic, and pharmaceutical industries. A notable characteristic is the colour transformation from milk white to light grey upon firing.

References

  1. Adekanmbi, A. (2005). "The Nigerian Steel Industry: Evolution and Raw Materials Development, with emphasis on Ajaokuta Steel Project". Foludex Press Ltd, Ibadan. p.172-188.
  2. Brady, N. C., & Weil, R. R. (2002). The nature and properties of soils. Prentice Hall.
  3. Bundy, W.M. (1993). "The Diverse Industrial Applications of Kaolin". In Murray, H.H., Bundy, W., and Harvey, C. (Editors) Kaolin Genesis and Utilization. Clay Mineral Soc. Boulder, colourado, Spec. Public. 1. 43-47
  4. Casagrande, A. (1948), "Plasticity Chart for Classification of Cohessive Soils", Transactions of American Society for Civil Engineering. Vol. 113, p. 901.
  5. Chesti A.R. (1994), "Refractories: Manufacture, Properties and Applications". Prentice-Hall of India, Private Limited, New Delhi, p. 55-63
  6. Dumont, E. (2003), "Clays", Canadian Minerals Yearbook (2003 Edition). P.19.1
  7. Ekosse, G. (1994). "Clays: A Gateway into The Future". Botswana Notes and Rec. 26. 139-149
  8. Ekosse, G.E. and Nkoma, J.S. (2000), "An Investigation of the Mineralogy, Physico-Chemistry and Plasticity of the Clayey material from the Makoro Kaolin Deposit, Botswana", Botswana Journal of Technology, October, p. 15-23.
  9. Grim, R. E. (1968). Clay mineralogy. McGraw-Hill.
  10. Grim R.E., (1962), "Applied Clay Mineralogy" McGraw-Hill, London, p 422.
  11. Grinshaw, R.W. (1971), "The Chemistry and Physics of Clay and Allied Ceramic Materials". 4th Edition. New Wiley-Interscience, London, England. p.15.
  12. Krynine, D.P. and Judd, W.R. (1957): Principles of Engineering Geology and Geotechnics. McGraw-Hill Civil Engineering Series, NY. Pp. 729
  13. Irabor, P.S.A. (2002), "Physical and Chemical Investigation on some Nigerian Kaolin clays for use in the ceramics and Allied Industries", Nigerian Journal of Engineering Research and Development, Vol. 1 No. 1, p. 54-59.
  14. Moore, D. M., & Reynolds, R. C. (1997). X-ray diffraction and the identification and analysis of clay minerals. Oxford University Press.
  15. Murray, H.H. (1960), Clay Industrial Minerals and Rocks, American Institute of Mining, Metal and Petroleum Engineers, New York, p. 259-284.
  16. Murray, H.H. (1986), "Clays Ulman's encyclopedia of Industrial Chemistry", Weinheim. Vol. 19. p. 67 - 89.
  17. Murray, R. C. (1986). Soil and land use planning. Cambridge University Press
  18. Nnuka, E.E. Elechikwu and Ogo, D.U.I. (1992), "Sustainable Refractory Sourcing for our Industries". In: Conference proceedings of NMS Annual Conference. p. 18-20.
  19. Nnuka, E.E. and Enejior, C. (2001), "Characterization of Nahuta Clay for Industrial and Commercial Applications". Nigerian Journal of Engineering Materials. Vol. 2. No. 3. p. 9-13.
  20. Oaikhinann, E.P. (1999), "Raw Materials Development in Nigeria in the Next Millennium", Interceram. Vol. 48 No. 6.
  21. Onaji, P.B. and Ahmed, K.S. (1995): Development of Ceramics in Nigeria. Nigeria Journal of Engineering. Vol. 7. 1. Pp. 1-12.
  22. Parker, E.R. (1967), "Materials Data Book for Engineers and Scientist", MacGraw-Hill Book Company, New York.
  23. Singer, F. and Singer, S.S. (1963), "Industrial Ceramics". Champion and Hall, London, p. 97-291, 465 -1180.
  24. Weaver, C.E. (1989), Clays, Muds and Shales, Developments in Sedimentology. Vol. 44. p. 819.
How to Cite

Y., A., & M., G. C. (2023). Mineralogical and Chemical Evaluation of Agbaja Fireclay for Industrial Applications. Nigerian Journal of Materials Science and Engineering, 13(1), 46-52.

A. Y., and G. C. M., "Mineralogical and Chemical Evaluation of Agbaja Fireclay for Industrial Applications," Nigerian Journal of Materials Science and Engineering, vol. 13, no. 1, pp. 46-52, June 2023.

Share this article:
Facebook X / Twitter LinkedIn